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1 article(s) from Deilhof, Konstantin

Thiophene-forming one-pot synthesis of three thienyl-bridged oligophenothiazines and their electronic properties

Dominik Urselmann,
Konstantin Deilhof,
Bernhard Mayer and
Thomas J. J. Müller

Beilstein J. Org. Chem. 2016, 12, 2055–2064, doi:10.3762/bjoc.12.194

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Graphical Abstract

Figure 1: Thienyl-bridged oligophenothiazines as topological hybrids of (oligo)phenothiazines and 2,5-di(hete...

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Scheme 1: One-pot bromine-lithium-exchange-borylation-Suzuki (BLEBS) synthesis of 7-bromo-substituted phenoth...

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Scheme 2: Pseudo five-component Sonogashira-Glaser-cyclization synthesis of thienyl-bridged oligophenothiazin...

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Figure 2: Cyclic voltammograms of compounds 3 (recorded in CH₂Cl₂, T = 293 K, electrolyte n-Bu₄N⁺PF₆⁻, Pt wor...

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Figure 3: UV–vis (solid lines) and fluorescence spectra (dashed lines) of the thienyl-bridged oligophenothiaz...

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Figure 4: DFT-calculated minimum conformer of the 2,5-bis(terphenothiazinyl)thiophene 3c (calculated with the...

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Figure 5: Relevant Kohn–Sham FMOs contributing to the S₁ states that are assigned to the longest wavelengths ...

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Published 20 Sep 2016

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